Aspects of this topic are discussed in the following places at Britannica.
...spectral lines caused by metals. The Sun is a class G star; these are yellow, with surface temperatures of 5,000–6,000 K. Class K stars are yellow to orange, at about 3,500–5,000 K, and M stars are red, at about 3,000 K, with titanium oxide prominent in their spectra. L brown dwarfs have temperatures between about 1,500 and 2,500 K and have spectral lines caused by alkali metals...
...the physical basis for all subsequent interpretations of stellar spectra. The spectral sequence is also a colour sequence: the O- and B-type stars are intrinsically the bluest and hottest; the M-, R-, N-, and S-type stars are the reddest and coolest.
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